Toledo is a municipality located in central Spain. It is the capital of the province of Toledo and the autonomous community of Castile-La Mancha. It was declared a World Heritage Site by UNESCO IN 1986. Toledo Spain Travel Guide A travel guide for the medieval city of Toledo in Spain. Toledo was the capital of Spain until the mid 1500's when the capital was moved to Madrid. Highlights include the Toledo Cathedral (Spain's largest Cathedral) built in the 13th century and the El Greco Museum. Toledo is an excellent day trip from Madrid and can be reached via a 33 minute high speed train ride from Atocha station.